Calorie (cal)

The calorie is a unit of energy equal to 4.184 joules. Its symbol is cal. It was originally defined as the heat needed to raise the temperature of one gram of water by one degree Celsius, and it is not an SI unit, though it survives almost everywhere that food and heat are discussed.

The original definition was awkward because the answer depends on the starting temperature. Water takes slightly more heat to warm from 14.5 to 15.5 degrees than from 19.5 to 20.5, so several competing calories existed: the fifteen-degree calorie, the mean calorie and the International Steam Table calorie among them. The thermochemical calorie now used is simply defined as exactly 4.184 joules, cutting the link to water entirely and ending the ambiguity.

The greater confusion is one of scale. The calorie printed on food packaging in the United States is not this unit at all but the kilocalorie, a thousand times larger, sometimes distinguished by a capital C. A biscuit described as containing sixty calories in fact contains sixty thousand of the unit described here. The convention is entrenched and unlikely to change, so nutritional figures and physical ones must be read in different registers.

Chemistry retained the calorie long after physics moved on. Enthalpies of reaction, bond energies and heats of formation were tabulated in kilocalories per mole for most of the twentieth century, and older literature and some current American textbooks still are. The equivalent SI figure in kilojoules per mole is larger by a factor of 4.184, and misreading which is meant produces errors that look plausible.

Nutrition science uses it because human energy balance happens to sit at a convenient scale in kilocalories, with a daily requirement of around two thousand. In joules the same figure is roughly eight and a half million, which is accurate but harder to reason with.

Air conditioning and refrigeration in some countries still rate capacity in kilocalories per hour, and heating values of fuels appear in calories per gram in older engineering tables.

One calorie equals exactly 4.184 joules, 0.001 kilocalories, or about 0.00116 watt-hours.

Calorie conversion table