Conversion from Calories to Watt-hours

Information about the Calorie (cal)

The calorie is a unit of energy equal to 4.184 joules. Its symbol is cal. It was originally defined as the heat needed to raise the temperature of one gram of water by one degree Celsius, and it is not an SI unit, though it survives almost everywhere that food and heat are discussed.

The original definition was awkward because the answer depends on the starting temperature. Water takes slightly more heat to warm from 14.5 to 15.5 degrees than from 19.5 to 20.5, so several competing calories existed: the fifteen-degree calorie, the mean calorie and the International Steam Table calorie among them. The thermochemical calorie now used is simply defined as exactly 4.184 joules, cutting the link to water entirely and ending the ambiguity.

The greater confusion is one of scale. The calorie printed on food packaging in the United States is not this unit at all but the kilocalorie, a thousand times larger, sometimes distinguished by a capital C. A biscuit described as containing sixty calories in fact contains sixty thousand of the unit described here. The convention is entrenched and unlikely to change, so nutritional figures and physical ones must be read in different registers.

Chemistry retained the calorie long after physics moved on. Enthalpies of reaction, bond energies and heats of formation were tabulated in kilocalories per mole for most of the twentieth century, and older literature and some current American textbooks still are. The equivalent SI figure in kilojoules per mole is larger by a factor of 4.184, and misreading which is meant produces errors that look plausible.

Nutrition science uses it because human energy balance happens to sit at a convenient scale in kilocalories, with a daily requirement of around two thousand. In joules the same figure is roughly eight and a half million, which is accurate but harder to reason with.

Air conditioning and refrigeration in some countries still rate capacity in kilocalories per hour, and heating values of fuels appear in calories per gram in older engineering tables.

One calorie equals exactly 4.184 joules, 0.001 kilocalories, or about 0.00116 watt-hours.

Information about the Watt-hour (Wh)

The watt-hour is a unit of energy equal to the energy delivered by one watt of power flowing for one hour, or exactly 3600 joules. Its symbol is Wh. It is the small change of the kilowatt-hour, used wherever quantities of energy are too modest to state in thousands.

Batteries are its main territory. The capacity of a laptop, phone, power tool or portable speaker is quoted in watt-hours, and this is the figure that matters when comparing devices, because it combines the two numbers usually printed on a cell. A battery marked 3000 milliampere-hours at 3.7 volts stores about 11 watt-hours, and the ampere-hour figure alone is meaningless without the voltage.

Aviation regulation has made the unit unexpectedly public. Lithium batteries above 100 watt-hours may not be carried in aircraft cabin baggage without airline approval, and above 160 watt-hours they are banned from passenger aircraft entirely. This is why laptop and camera batteries carry the figure printed on them, and why portable power banks are designed to sit just under the threshold.

Small-scale energy generation uses it as well. A solar panel on a garden light, an energy-harvesting sensor or a bicycle dynamo produces watt-hours per day rather than kilowatt-hours, and low-power electronics designed to run for years on a single cell are budgeted in milliwatt-hours.

The unit shares the criticism levelled at the kilowatt-hour: it combines a coherent SI unit of power with a non-SI unit of time. In strictly SI terms the correct expression is 3600 joules, or 3.6 kilojoules, and scientific writing uses joules. Everywhere else the practical link to a device's power rating wins.

Energy storage systems, from a home battery to a grid installation, scale upward through kilowatt-hours and megawatt-hours from the same starting point, so the whole family shares one arithmetic.

A common confusion is worth clearing up here. Battery cells are usually labelled in ampere-hours or milliampere-hours, which measure charge and not energy, and two cells with the same ampere-hour rating store quite different amounts if their voltages differ. Multiplying ampere-hours by the nominal voltage gives watt-hours: a 3000-milliampere-hour phone cell at 3.85 volts holds about 11.6 watt-hours. That is why capacity comparisons between devices are only meaningful in watt-hours, why airlines set their limits in watt-hours, and why a power bank advertised in milliampere-hours may deliver less than its number suggests once its own conversion losses are counted.

One watt-hour equals 3600 joules, 0.001 kilowatt-hours, or about 0.86 kilocalories.