Conversion from Watt-hours to Electronvolts

Information about the Watt-hour (Wh)

The watt-hour is a unit of energy equal to the energy delivered by one watt of power flowing for one hour, or exactly 3600 joules. Its symbol is Wh. It is the small change of the kilowatt-hour, used wherever quantities of energy are too modest to state in thousands.

Batteries are its main territory. The capacity of a laptop, phone, power tool or portable speaker is quoted in watt-hours, and this is the figure that matters when comparing devices, because it combines the two numbers usually printed on a cell. A battery marked 3000 milliampere-hours at 3.7 volts stores about 11 watt-hours, and the ampere-hour figure alone is meaningless without the voltage.

Aviation regulation has made the unit unexpectedly public. Lithium batteries above 100 watt-hours may not be carried in aircraft cabin baggage without airline approval, and above 160 watt-hours they are banned from passenger aircraft entirely. This is why laptop and camera batteries carry the figure printed on them, and why portable power banks are designed to sit just under the threshold.

Small-scale energy generation uses it as well. A solar panel on a garden light, an energy-harvesting sensor or a bicycle dynamo produces watt-hours per day rather than kilowatt-hours, and low-power electronics designed to run for years on a single cell are budgeted in milliwatt-hours.

The unit shares the criticism levelled at the kilowatt-hour: it combines a coherent SI unit of power with a non-SI unit of time. In strictly SI terms the correct expression is 3600 joules, or 3.6 kilojoules, and scientific writing uses joules. Everywhere else the practical link to a device's power rating wins.

Energy storage systems, from a home battery to a grid installation, scale upward through kilowatt-hours and megawatt-hours from the same starting point, so the whole family shares one arithmetic.

A common confusion is worth clearing up here. Battery cells are usually labelled in ampere-hours or milliampere-hours, which measure charge and not energy, and two cells with the same ampere-hour rating store quite different amounts if their voltages differ. Multiplying ampere-hours by the nominal voltage gives watt-hours: a 3000-milliampere-hour phone cell at 3.85 volts holds about 11.6 watt-hours. That is why capacity comparisons between devices are only meaningful in watt-hours, why airlines set their limits in watt-hours, and why a power bank advertised in milliampere-hours may deliver less than its number suggests once its own conversion losses are counted.

One watt-hour equals 3600 joules, 0.001 kilowatt-hours, or about 0.86 kilocalories.

Information about the Electronvolt (eV)

The electronvolt is a unit of energy equal to the work done on a single electron moved through a potential difference of one volt. Its symbol is eV. Since the 2019 redefinition of the SI it has an exact value, 1.602176634 times ten to the power minus nineteen joules, because the elementary charge itself is now a defined constant.

It exists because the joule is hopelessly large for the atomic world. A single visible photon carries between about 1.6 and 3.3 electronvolts, and expressing that in joules requires nineteen leading zeros. Working in electronvolts lets a physicist state the energy of a chemical bond, an atomic transition or a subatomic collision as a number between one and a few, which is what a unit is supposed to do.

The scale organises whole disciplines. Chemistry lives at a few electronvolts, the energy of bonds and of the visible and ultraviolet photons that break them. X-rays occupy kiloelectronvolts. Nuclear physics works in megaelectronvolts, the scale of binding energies and radioactive decay. Particle physics uses gigaelectronvolts, where the proton's rest mass is 0.938, and teraelectronvolts at the Large Hadron Collider, whose protons carry 6.8 each.

Mass is quoted in the same unit through the mass-energy relation. A particle's rest mass is given in electronvolts divided by the speed of light squared, and physicists routinely drop the divisor and simply say that the electron is 511 kiloelectronvolts. The Higgs boson is 125 gigaelectronvolts on the same convention.

Semiconductor engineering depends on it. The band gap that determines what a material does electrically and optically is an energy in electronvolts: about 1.1 for silicon, 3.4 for gallium nitride, and this single number decides whether a device is a solar cell, a transistor or a blue light-emitting diode.

Astronomy inherits the convention for high-energy photons, so gamma-ray telescopes report observations in gigaelectronvolts and teraelectronvolts rather than in wavelengths.

Particle accelerators are named after the energies they reach, which is why their names track the prefixes. The Cockcroft-Walton machine that first split a nucleus in 1932 worked at a few hundred kiloelectronvolts; the Bevatron of the 1950s reached billions and found the antiproton; and the Large Hadron Collider brings protons to 6.8 teraelectronvolts each. Cosmic rays put all of this in perspective by arriving with energies up to 10 to the twentieth electronvolts, tens of millions of times more than any machine can produce, though only a handful of such particles strike the Earth in a century over a square kilometre.

One electronvolt equals about 1.602 times ten to the power minus nineteen joules, or roughly 3.83 times ten to the power minus twenty calories.