Atmosphere (atm)

The atmosphere is a unit of pressure defined as exactly 101,325 pascals. Its symbol is atm. It is not a measurement of the air at any particular place or moment but a fixed reference value, chosen in 1954 by the General Conference on Weights and Measures to sit close to the average pressure at sea level in temperate latitudes.

Its usefulness is that it turns pressure into a ratio. Saying that a vessel holds gas at six atmospheres says immediately that the pressure inside is six times what is outside, which is the fact that determines whether a container will burst, how much gas it holds and how fast it will empty. No other pressure unit carries that meaning in the number itself.

Chemistry built its early framework on it. Gas laws were written with pressures in atmospheres, the gas constant had a value tailored to litres and atmospheres, and standard conditions for tabulating thermodynamic data were defined at one atmosphere. In 1982 the International Union of Pure and Applied Chemistry changed the standard state to exactly one bar, so modern tables use bar and older ones use atmospheres, and the difference of 1.3 per cent matters in careful work.

Diving and hyperbaric medicine still count in it. Pressure underwater is described in atmospheres absolute, a diver at thirty metres experiencing about four, and hyperbaric oxygen therapy is delivered at two to three atmospheres absolute in a sealed chamber. Because gas volume and gas uptake by the body both scale with absolute pressure, the unit is doing real physiological work rather than merely reporting a reading.

The atmosphere also fixes the older mercury scales. One atmosphere is exactly 760 millimetres of mercury by definition, which is what ties the torr and the millimetre of mercury to the metric system, and it is 29.92 inches of mercury, the setting an American pilot dials into an altimeter as standard.

A related unit, the technical atmosphere of one kilogram-force per square centimetre, is close but not equal at 98,066.5 pascals. Documents from Japan, Korea and eastern Europe sometimes use it, and mistaking one for the other introduces an error of about three per cent.

One atmosphere equals 101,325 pascals, 1.01325 bar, 760 millimetres of mercury, or about 14.696 pounds per square inch.

Atmosphere conversion table